17.7.2.1 Ballistic protection
Ballistic protection concerns apparel, vests, armors, helmets, and structural reinforcement for vehicles as well. The woven, knitted or nonwoven fabrics, laminates, and composites are used for ballistic protection. The type (knife, hand gun, assault rifle bullet, high-velocity bullet) and level of the threat are considered in design and manufacturing of ballistic protective apparel. The structure of armors may include ceramic plates, special fibers/textile structures, laminated/coated textiles, and composites depending on these parameters. In addition, blunt impact protection could be imparted to armors by including shock-absorbing materials.
Different types of body armor used for ballistic protection and different materials and structures used for body armor, the test methods used for the evaluation of ballistic performance, government regulations related to the manufacturing and use of protective clothing, and the methods of testing in several countries of the world have been described (Wang, Kanesalingam, Nayak, & Padhye, 2014).
In terms of textiles, ballistic protection can be divided into two broad categories: soft, “wearable” armor, wherein the ballistic protection is provided by the soft, flexible textile, and soft-rigid armor, wherein ballistic protection is provided by a combination of inflexible armor plates that are integrated into a high-modulus textile. Soft-rigid composite textile systems for ballistics protection typically comprise ceramic armor plates, for example, boron nitride, tungsten carbide, tungsten disulfide, aluminum nitride, and so forth, coated or contained in high-modulus organic polymers, such as para-aramids, for example, Kevlar and Twaron, or UHMW polyolefins, for example, Spectra and Dyneema (https://www.ncjrs.gov/pdffiles1/nij/247281.pdf) (Owens, 2011).
In such systems, rigid plates are designed to intercept an incoming projectile and disperse its kinetic energy over a large area, while the soft textile is used to disperse as much kinetic energy as possible and cause deformation of the round prior to it reaching the ceramic plates (Owens, 2011). Another technology that has demonstrated the ability to serve in an antiballistic capacity is a composite system consisting of a high-performance antiballistic fiber combined with a shear-thickening colloidal dispersion. Shear-thickening fluids or STFs are liquids whose viscosity increases as a function of applied stress. A mixture of cornstarch and water is the classic example of an STF. Researchers at the University of Delaware have produced antiballistic yarns possessing STFs intercalated into the fiber (Owens, 2011) (Wagner & Brady, 2009).
Ballistic tests of these composite fibers show a 250% increase in stopping power of STF-treated Kevlar fibers compared to Kevlar alone. Production of these STF-enhanced textiles for other applications has already begun by Dow Corning under the name Deflexion. Now, consider a merger of M-5 fiber with STF technology and it becomes apparent that soft antiballistic armor will soon be a reality (Owens, 2011). The protective power of typical aramid-based multilayered ballistic fabrics designed to defeat high-velocity ballistic impacts can be improved if wool is incorporated into the weave structure. Ballistic tests have shown that synthetic fabrics blended with wool can at least match the dry or wet ballistic performance of an equivalent pure Kevlar fabric when tested under National Institute of Justice (NIJ) (2014) Ballistic Standard Level III A. The inclusion of the wool can significantly improve the tear strength of pure synthetic ballistic fabrics (Sinnppoo, Arnold, & Padhye, 2010). The use in range of wool fiber and its blends can be increased and further explored for technical textiles applications. Tegris® is a thermoplastic 100% polypropylene composite for hard and soft armor applications, including personal body armor, vehicle armor, blast blankets, and a number of other armor-related applications to counter fragment, projectile, and blast threats (http://millikenmilitary.milliken.com/en-us/technologies/Pages/composites.aspx).
For lightweight stiffness, TYCOR-reinforced core materials are comprised of closed cell foam wrapped in fiberglass. When laid in a mold and infused with resin, TYCOR becomes a stiff, strong material lighter then infused balsa. TYCOR can be used in a variety of applications including bridges, boats, submarine camels, and more (http://millikenmilitary.milliken.com/en-us/products/Pages/impact-resistant-composites.aspx).
The US Army is experimenting with new, advanced composites, to improve vehicle and body armor, providing lighter and more effective protection from different threats, including bullets, fragments, IEDs, and mines. One of the most promising materials is the new high-strength M5 fiber, developed by Akzo Nobel central research labs and currently produced by Magellan Systems International. It has an extraordinary potential for use in armor systems for personnel and vehicles, flame and thermal protection, as well as in high-performance structural composites. Potential Army applications of the fiber include fragmentation vests and helmets, composites for use in conjunction with ceramic materials for small arms protection and structural composites for vehicles and aircraft. It enables the fabrication of advanced lightweight composites into hard and soft ballistic armor. M5 offers significant advantages over both steel and carbon, which is currently used for fabrication of aerospace and automotive structural parts (http://defense-update.com/products/m/m-5-fiber.htm).
M5 fiber is based on the rigid-rod polymer poly{diimidazo pyridinylene (dihydroxy) phenylene}; M5 fiber-based armor has the potential to substantially decrease the weight of body armor while enhancing or maintaining impact performance. Composite fragmentation armor systems were developed using less than optimal quality M5 fiber and tested under ballistic impact; the performance of these armor systems was exceptional. The crystal structure of M5 is different from all other high-strength fibers; the fiber not only features typical covalent bonding in the main chain direction, but it also features a hydrogen bonded network in the lateral dimensions. M5 fibers currently have an average modulus of 310 GPa, (i.e., substantially higher than 95% of the carbon fibers sold), and average tenacities currently higher than aramids (such as Kevlar or Twaron) and on a par with PBO fibers (such as Zylon), at up to 5.8 GPa. Based on these results, it is estimated that fragmentation protective armor systems based on M5 will reduce the areal density of the ballistic component of these systems by approximately 40%–60% over Kevlar KM2 fabric at the same level of protection (Cunniff & Auerbach, http://web.mit.edu/course/3/3.91/www/slides/cunniff.pdf).
The central tasks of ballistic protection are the absorption and the dissipation of energy caused by a ballistic impact. For this reason, bulletproof vests generally consist of a number of layers. Their fabrics or composite layups are made of yarns of high-performance fibers. At the impact of a bullet the material absorbs the kinetic energy—a handgun projectile travels at a speed of 400 m a second—by stretching of fibers and other stiff fibers which disperse the load over a large area throughout the material. This slows the bullet down and finally hinders it from penetrating the body. Body armor designed specifically to defeat rifle fire has to be more rigid, because those projectiles travel at speeds of around 800 m a second. Therefore, besides the layers with fibers, hard materials such as ceramics or metal plates have to be inserted. The protective plates absorb and dissipate this greater kinetic energy upon impact and also the bullet itself gets blunted.
Carbon nanotube fibers woven as a cloth or incorporated into the polymer matrix composite materials are also reported to improve the ballistic performance and enhance stiffness, strength, and toughness against the most aggressive ballistic threats.
DuPont has developed its next generation of bullet-resistant Kevlar fiber that is stronger and lighter than previous versions. Kevlar XP promises to stop 44 Magnum rounds in the first two to three layers of an 11-layer vest, according to DuPont and independent lab tests. While that is impressive, DuPont says it can do this with 10% less weight and 15% less backface deformation which directly translates into less blunt force trauma to vest wearers. While 10% less weight may not sound like much, police officers and soldiers are grateful for a lighter vest, especially when they have to wear tens or even hundreds of pounds of extra gear.
The nature of protective clothing means that there are naturally similarities between different products. For example, there are a number of similarities between bulletproof and stabproof vests, including materials and design. This may seem obvious, but even Turnout Gear shares a number of similarities with bulletproof vests, beyond that both are used to protect an individual. Even their design and development follow similar paths due to the desired end result. Kevlar is not only incredibly strong, but is lightweight and flexible. This is why it is so heavily favored in body armor manufacture. However, aramids are also capable of withstanding extreme temperatures, and will not melt or degrade at temperatures up to 800°F. This means that Kevlar has also found use in Turnout Gear, although aramid manufacturers often look to provide materials with far higher heat resistance, usually at the expense of some ballistic protection. Nevertheless, Kevlar does find uses in Turnout Gear, offering some protection against impacts and blunt trauma. Some manufacturers offer blends of materials, for example, a mixture of Kevlar and Nomex, another aramid material from DuPont that has a far higher resistance to heat. By producing a blend the material can offer the heat resistance needed by firefighters while also decreasing friction and improving co-operation between the layers of Turnout Gear.